Unit 3: Intermolecular Forces and Properties

Molarity and Solution Concentration

How do chemists describe how much solute is dissolved in a solution?

24 min
High School Chemistry / AP Chemistry
5 source chapters

Learning Objectives

  • Define molarity as moles of solute per liter of solution.
  • Calculate molarity from moles and volume.
  • Rearrange M = n / V to solve for moles or volume.
  • Explain why solution volume, not solvent volume alone, is used in molarity.
  • Interpret concentration at the particle level.

What concentration means

Concentration compares how much solute is present to how much solution there is. A concentrated solution has more solute particles in the same volume than a dilute solution.

Molarity as a ratio

Molarity is a ratio: moles of solute divided by liters of solution. The denominator is total solution volume because the final mixture is what particles occupy.

Same solute, different volume

Imagine the same number of dissolved particles spread through two beakers. In the smaller volume, particles are closer together, so the concentration is higher.

Two beakers with equal solute particles but different solution volumes.

Molarity equation

Use liters of solution in the denominator. Convert milliliters to liters before substituting.

M = n / V
  1. 1M is molarity in mol/L, often written as M.

Worked Example

Calculate molarity

What is the molarity of a solution containing 0.500 mol NaCl in 2.00 L of solution?

Quick Check

Two solutions contain the same moles of solute. Which one is more concentrated?

Quick Check

How many moles of solute are in 0.750 L of a 0.200 M solution?

Misconception Check

Misconception: Molarity is grams of solute divided by water volume.

Correction: Molarity uses moles of solute divided by liters of final solution. If grams are given, convert grams to moles first.

Key Terms

solution

溶液

A homogeneous mixture of solute and solvent.

solute

溶质

The substance dissolved in a solution.

solvent

溶剂

The substance that dissolves the solute.

molarity

物质的量浓度

Moles of solute per liter of solution.

concentration

浓度

How much solute is present in a given amount of solution.

dilution

稀释

Adding solvent to lower concentration while solute amount stays the same.

Summary

  • Molarity is moles of solute per liter of solution.
  • Use liters in M = n / V.
  • The final solution volume is the denominator.
  • Higher molarity means more solute particles per liter.

Practice bridge

Convert 250. mL to liters, then calculate the molarity of 0.100 mol KBr in that volume.

Explain your answer using both the equation and a particle-level picture.

Related Resources

Marker chapters

  • Chemistry 11e By Steven Zumdahl, DeCoste/Chapter 11- Properties of Solutions
  • Chemistry 14e by Raymond Chang Jason Overby/Chapter 04 - Reactions in Aqueous Solutions
  • Chemistry 14e by Raymond Chang Jason Overby/Chapter 12 - Physical Properties of Solutions
  • Chemistry The Central Science in SI Units 15th Global Edition/Chapter 13- Properties of Solutions
  • Chemistry 11e By Steven Zumdahl, DeCoste/Chapter 4- Types of Chemical Reactions and Solution Stoichiometry

Optional downloads

  • molarity_solution_concentration_student_handout.md
  • molarity_solution_concentration_teacher_guide.md
  • molarity_solution_concentration_qa_report.md

Practice Bridge

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Teacher note: source-grounded draft reviewed for chemistry accuracy; final classroom use should still check local textbook excerpts.